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Evidence for a ruthenium dihydride species as the active catalyst in the RuCl2(PPh3)-catalyzed hydrogen transfer reaction in the presence of base
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- Aranyos, A (author)
- Uppsala universitet
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- Csjernyik, G (author)
- Uppsala universitet
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- Szabo, KJ (author)
- Uppsala universitet
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- (creator_code:org_t)
- ROYAL SOC CHEMISTRY, 1999
- English 351-352 s.
- In: CHEMICAL COMMUNICATIONS. - : ROYAL SOC CHEMISTRY. ; :4
- Other publication (other academic/artistic)
Abstract
Subject headings
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- The role of the base in RuCl2(PPh3)(3)-catalyzed hydrogen transfer reactions is to generate a highly active RuH2(PPh3)(3) catalyst from the dichloride via two consecutive alkoxide displacement-beta-elimination sequences.
Keyword
- ENANTIOSELECTIVE TRANSFER HYDROGENATION; ASYMMETRIC TRANSFER HYDROGENATION; PHOSPHINE COMPLEXES; HIGHLY EFFICIENT; CHIRAL LIGANDS; KETONES; REDUCTION; PROPAN-2-OL; ALCOHOLS; POLYHYDRIDES
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- vet (subject category)
- ovr (subject category)
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- Uppsala University
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